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Vibrational motion in the local- and normal-mode pictures

โœ Scribed by H.S. Moller; O.Sonnich Mortensen

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
548 KB
Volume
66
Category
Article
ISSN
0009-2614

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๐Ÿ“œ SIMILAR VOLUMES

Between the local-mode and normal-mode l
Between the local-mode and normal-mode limits
โœ A.C. Scott; P.S. Lomdahl; J.C. Eilbeck ๐Ÿ“‚ Article ๐Ÿ“… 1985 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 639 KB

A simple model system is introduced for the vibrational analysis of polyatomic molecules. Y~US classical system is based on complex mode amplitudes and reduces to either the normal-mode (NM) or the localmode (LM) description in appropriate Limits. Upon analysis without perturbative assumptions, the

Local mode and normal mode interpretatio
Local mode and normal mode interpretations of the CH and CD stretching vibrational manifolds of 1,1-dideuteroethene
โœ J.L. Duncan; I.M. Mills ๐Ÿ“‚ Article ๐Ÿ“… 1988 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 463 KB

The =CHI and =CD2 stretching vibrational overtones of H&-CD2 have been studied up to V= 6 and V= 3, respectively. We report their interpretation in terms of a transition from normal to local modes, involving Fermi resonance with the C-C stretching and CHz scissoring vibrations. We discuss the altern