Vibrational heating effects in the flash photolysis of ozone

✍ Scribed by J.A. Hanvey; W.D. McGrath

• Publisher: Elsevier Science
• Year: 1975
• Tongue: English
• Weight: 481 KB
• Volume: 36
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(75)85338-3

✦ Synopsis

The vibralional rcmperaturc oi ozone hns been estimated during the flash photolvsis of ozone under non-isothermal nnd strictly isothermal conditions, utilisin:! the variation in extinction coefficient with temperature 31 two lv'avelen$hs. Vibrational tcmpera!urcs me;isurcd in the range 300-970 K have been attributed to energy transfer from 0t(3~J to ozone and the effect of this non-equilibrium vibrational cscitatioll on the secondary reactions with non-zero activation cncrgies is discussed.