Vibrational energy transfer from N2 to CO on electron excitation of N2-CO solids at 4.2 K
✍ Scribed by W.W. Duley; O. Oehler; D.A. Smith
- Publisher
- Elsevier Science
- Year
- 1975
- Tongue
- English
- Weight
- 380 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Spectra emitted from 0.15 CO-N; solids escited with high encrg elccirons at 4 R show evidence for rcsonant transfer of vibrational &qry from highly excited vibrational levels of N, to Coin the process,Nz(XI z'&, v) + CO(u = 0) --F N,(X'ZL, Y -1) + C0(11= 1) + phonons. Enqg transfer from levels with Y < 9 has been observed.
📜 SIMILAR VOLUMES
New experimental time-of-flight distributions arc reported for Lith'z and Li+-CO at two center-of-mass enc&s of about 8 and 16 eV and large scattering anples elab =Z 120°. The Li+--h'z spectra sho\v two widely spaced maxima, whereas the Li+-CO spectra show two and sometimes three maxima. The results
## Abstract An approximate analytical solution of relaxation in a low‐pressure system with exponential transition probabilities is given for vibrational–rotational energy transfer in the dissociation of diatomics. The main assumption is that the rotational degrees of freedom are in thermal equilibr