Vibrational energy transfer according to the morse potential: Application to self-relaxation of methane

✍ Scribed by H. Ulrich; P. Hess

• Publisher: Elsevier Science
• Year: 1979
• Tongue: English
• Weight: 328 KB
• Volume: 61
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(79)80667-3

✦ Synopsis

The pemrbation integral in the semiclassica! theory of vibrational energy transfer is derived ia closed form for a Morse potentiaL The temperature dependence of V-T transfer in CH4-CH4 ccllisioas is investigated, using a recently published numerical CHa potential to determin e the parameters of the Morse potentiaL