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Vibrational Energy Relaxation of the OH Stretch in Liquid Methanol

โœ Scribed by Gulmen, Tolga S.; Sibert, Edwin L.


Book ID
126445535
Publisher
American Chemical Society
Year
2004
Tongue
English
Weight
185 KB
Volume
108
Category
Article
ISSN
1089-5639

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Observation of site-dependent relaxation
โœ J.R. Engholm; U. Happek; A.J. Sievers ๐Ÿ“‚ Article ๐Ÿ“… 1996 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 341 KB

We have investigated the vibrational relaxation of the OH impurity stretch mode in amorphous SiO 2. At low temperatures, a short relaxation time of ~-10-l0 s is found that varies strongly across the inhomogeneously broadened absorption line. The inhomogeneous broadening is caused by a site-dependent