Preliminary results arc reported of a Monte Carlo trajectory study of intramolecular vibrational ener\_w relaxation in a model of benzene. Very little relaxation 1s found to occur on d picosecond timeswle. The rate of intramolecular wbrational energy relaxation appears to be dependent upon the natur
โฆ LIBER โฆ
Vibrational energy relaxation in benzene and some benzene substitutes
โ Scribed by A. Fendt; S.F. Fischer; W. Kaiser
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 548 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The energy decay of CH-stretchmg modes is measured for the molecules C6H6, C6HsC1. C&sCHB, C&&(CI-Ks j2, and CsNHs in the liquid phase. The observed lifetimes vary between f and 2 ps. In the theoretical analysis, three fast decay mechanisms are discussed_
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