The Iow-lying electronic energy levels of the divnlcnt colx~it ion in doped isomorphic single crystals of CdC12, CdBr2 nnd MnClZ have been measured at low temperatures by means of the Lkxtxm effect. 'She observed energies, which arc markedly concentration dcpcndent, arc ussigned to transitions withi
Vibrational electronic coupling in a spin forbidden band of Co2+ IN CdCl2
β Scribed by A. Mooney; R.H. Nuttall; W.E. Smith
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- English
- Weight
- 161 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The high resolution spectrum of B spin forbidden band, 4T,,(F) + 'Tlg(P), in Co2+/CdClz at 4.2OK is reported. A great deal of fine structuxc is observed some of which can be rntionalised in terms of vibronic coapline, with a low lying acoustic mode of CdCI,.
π SIMILAR VOLUMES
The standard INDC method has been used to calculate the e!cctron spin density distribution and isotropic Fermi contact hypcrfine coupling in the radicals CO+, COT, and OF. Bond lengths and angle (for CO?:) have been varied over a rcasonable ranpe. Geomctricnl effects arc found to have a rclativcly s
High-resolution Fourier transform spectra covering the \(720-920 \mathrm{~cm}^{-1}\) spectral region have been used to perform a reanalysis of the \(\nu_{2}\) band \(((010)-(000)\) vibrational transition \()\) together with the first analysis of the \(2 \nu_{2}-\nu_{2}\) hot band of nitrogen dioxide