Vibrational assignments of N,N-bis(3,5-dimethyl-2-hydroxybenzyl)methylamine in the fingerprint region
✍ Scribed by J Dunkers; H Ishida
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 663 KB
- Volume
- 51
- Category
- Article
- ISSN
- 1386-1425
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✦ Synopsis
The compound N,N-bis (3,5-dimethyl-2-hydroxybenzyl)methylamine is synthesized to model the phenolic resulting from ring opening polymerization of benzoxazine monomers. Fundamental vibrational assignments of N,N-bis(3,5-dimethyl-2-hydroxybenzyl)methylamine are made by the analysis of the fingerprint region (2000-500 cm t) of the infrared and Raman spectra of crystalline, quenched, and molten dimers. In addition, the hydrogens in the methylene bridge structure are deuterated to provide insight into vibrations due to the presence of the bridge structure. The structure of hydrogenated and deuterated model dimers is verified by tH and ~3C nuclear magnetic resonance spectroscopy.
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## Abstract EPR Spectra have been measured for aqueous solutions of a series of Gd^3+^ complexes at variable temperature and a range of magnetic fields; S‐band (0.14 T), X‐band (0.34 T), Q‐band (1.2 T), and 2‐mm‐band (5.0 T). The major contribution to the observed line widths is magnetic‐field‐depe