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Vibrational assignments of N,N-bis(3,5-dimethyl-2-hydroxybenzyl)methylamine in the fingerprint region

✍ Scribed by J Dunkers; H Ishida


Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
663 KB
Volume
51
Category
Article
ISSN
1386-1425

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✦ Synopsis


The compound N,N-bis (3,5-dimethyl-2-hydroxybenzyl)methylamine is synthesized to model the phenolic resulting from ring opening polymerization of benzoxazine monomers. Fundamental vibrational assignments of N,N-bis(3,5-dimethyl-2-hydroxybenzyl)methylamine are made by the analysis of the fingerprint region (2000-500 cm t) of the infrared and Raman spectra of crystalline, quenched, and molten dimers. In addition, the hydrogens in the methylene bridge structure are deuterated to provide insight into vibrations due to the presence of the bridge structure. The structure of hydrogenated and deuterated model dimers is verified by tH and ~3C nuclear magnetic resonance spectroscopy.


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