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Vibrational and Rotational Distributions of the CH(A 2 Δ) Product of the C 2 H + O( 3 P) Reaction Studied by Fourier Transform Visible (FTVIS) Emission Spectroscopy

✍ Scribed by Chikan, Viktor; Leone, Stephen. R.


Book ID
126476539
Publisher
American Chemical Society
Year
2005
Tongue
English
Weight
203 KB
Volume
109
Category
Article
ISSN
1089-5639

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Formation of methyl radicals via the consecutive reactions H+C2H,+M+C2H,+M ( I ) and H+CLH,+CH,+CH3 (?a) was initiated by pulse radiolysis of IO-100 mbar Hz in the presence of ethylene. The kinetics of CH, were studied by monitoring the transient infrared absorption at the Q( 3, 3) line of the u,=O+