Vibrational and reorientationl relaxation in liquid tert-butyl bromide and tert-butyl bromide-d9
β Scribed by R. Szostak; J.P. Hawranek
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 367 KB
- Volume
- 275
- Category
- Article
- ISSN
- 0022-2860
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π SIMILAR VOLUMES
Collision energy dependence of the Penning ionization cross-section for the Kr( 3 P) + (CH 3 ) 3 CBr ! Kr + (CH 3 ) 3 CBr ΓΎ + e Γ reaction was determined under orientation-angle resolved condition using an oriented (CH 3 ) 3 CBr beam and time-of-flight measurements. A remarkable resonance-type struc
Changes in the magnitude of (AEdOwn), the average downward collisional energy transferred between a highly vibrationally excited reactant molecule and an inert bath gas, upon perdeuteration of the substrate are reported for tert-butyl bromide dilute in Ar, Kr, N,, and CO,. The technique of pressure-
## Abstract ^1^H, ^2^H and ^14^N NMR line widths and spinβlattice relaxation times (__T__~1~) of __tert__βbutyl cyanide (TBCN) were measured at a field strength of 9.4 T in the liquid and solid states. The NMR line width data reveal the existence of two crystalline phases between 160 K and the melt