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Vibrational analysis of the products from thermal decomposition of OCS and CO2

✍ Scribed by John A. Chenery; Asghar Fakhr; Malcolm I. Wood; C.J.S.M. Simpson


Publisher
Elsevier Science
Year
1983
Tongue
English
Weight
717 KB
Volume
96
Category
Article
ISSN
0009-2614

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✦ Synopsis


The thermal decomposition of CO2 and OCS has been studied using a shock tube and cw CO probe Iaser. The energies of activation are in good agreement with the values of other workers. It has been shown that the CO formed from OCS hds an initial non-thermal vibrational distribution with a large excess in u = 0.


πŸ“œ SIMILAR VOLUMES


The rotational distribution of OCS+(Γƒ 2Ξ 
✍ Hiroshi Obase; Masaharu Tsuji; Yukio Nishimura πŸ“‚ Article πŸ“… 1987 πŸ› Elsevier Science 🌐 English βš– 391 KB

OCS+ (x-z) emission has heen observed from the thermal energy charge transfer reaction between N; ions and OCS molecules. The rotational temperatures of the OCS+ (A 21T,: O") state were estimated to be 23OOk 300 K for D = 3/2 and 3300 + 500 K for O= 112, by assuming a single Boltzmann distribution.