Vibrational analysis of the products from thermal decomposition of OCS and CO2
β Scribed by John A. Chenery; Asghar Fakhr; Malcolm I. Wood; C.J.S.M. Simpson
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 717 KB
- Volume
- 96
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The thermal decomposition of CO2 and OCS has been studied using a shock tube and cw CO probe Iaser. The energies of activation are in good agreement with the values of other workers. It has been shown that the CO formed from OCS hds an initial non-thermal vibrational distribution with a large excess in u = 0.
π SIMILAR VOLUMES
OCS+ (x-z) emission has heen observed from the thermal energy charge transfer reaction between N; ions and OCS molecules. The rotational temperatures of the OCS+ (A 21T,: O") state were estimated to be 23OOk 300 K for D = 3/2 and 3300 + 500 K for O= 112, by assuming a single Boltzmann distribution.