Vibrational analysis of 2,2-dichloropropane and 2,2-dichloropropane-d6
β Scribed by G.A. Crowder
- Book ID
- 108007275
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 189 KB
- Volume
- 42
- Category
- Article
- ISSN
- 1386-1425
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π SIMILAR VOLUMES
The thermal decomposition of 1,2-dichloropropane at atmospheric pressure has been studied in the temperature range 227-59OoC, in a flow system. Above 45OoC, the reaction is homogenous and unimolecular with a rate constant: Below 45OoC, a low activation energy, probably heterogenous process competes
Proton and "C line widths and spin-lattice relaxation times, TI, have been measured for liquid and solid 2,2-dichloropropane (1) and 2,2-dibromopropane (2). Molecular self-diffusion, with activation energies in the range 18-24 kJ mol-', is responsible for the considerable line narrowing observed for