The energy decomposition analysis of Morokuma and Kitaura-Morokuma is used to clucidatc the origin of the rotational barrier. The barrier of ethane, defined as the difference between the methyl radical-methyl radical interaction energy in a staggered and an eclipsed conformation, is found to be domi
β¦ LIBER β¦
Vibrational analyses and barriers to internal rotation of CH3CCl2F and CH3CHClF
β Scribed by J.R. Durig; C.J. Wurrey; W.E. Bucy; A.E. Sloan
- Book ID
- 113373666
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 472 KB
- Volume
- 32
- Category
- Article
- ISSN
- 1386-1425
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Collisional deactivation of by the title compounds was investigated through 2 I( P ) 1/2 the use of the time-resolved atomic absorption of excited iodine atoms at Rate 206.2 nm. constants for atomic spin-orbit relaxation by CH 3 Cl, CH 2 Cl 2 , CHCl 3 , CCl 3 F, and CCl 4 are and Οͺ13 Οͺ13 Οͺ14 Οͺ15 3.