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Vibration wavenumbers of 4-aminobenzotrifluoride in the ground and S1 electronic states from its supersonic jet S1-S0 fluorescence, infrared, and Raman spectra

✍ Scribed by Paulo J.A. Ribeiro-Claro; JoséJ.C. Teixeira-Dias; Robert D. Gordon; J.Michael Hollas

Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
732 KB
Volume
149
Category
Article
ISSN
0022-2852

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Vibration Wavenumbers of 2-Aminobenzotri
Vibration Wavenumbers of 2-Aminobenzotrifluoride in the Ground and S1 Electronic States from Its Infrared, Raman, and Supersonic Jet S1-S0 Fluorescence Spectra
✍ P.J.A. Ribeiroclaro; J.J.C. Teixeiradias; R.D. Gordon; J.M. Hollas 📂 Article 📅 1993 🏛 Elsevier Science 🌐 English ⚖ 383 KB

Raman and infrared spectra of 2-aminobenzotrifluoride, in the liquid phase, and single vibronic level fluorescence (SVLF) spectra, in a supersonic jet, have been recorded and assigned to give an almost complete set of fundamental vibration wavenumbers in \(S_{0}\). In the SVLF spectrum, the assignme

CF3-torsional potentials of 2-aminobenzo
CF3-torsional potentials of 2-aminobenzotrifluoride in the S0 and S1 electronic states from fluorescence spectra in a supersonic jet
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Both fluorescence excitation and dispersed fluorescence spectra of 2-aminobenzotrifluoride in a supersonic jet show quite extensive vibrational structure due to the CF,-torsional motion in the S, and So electronic states, respectively. This structure has been assigned and results in CF,-torsional po