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Vibration rotation Raman spectroscopy of gas media

✍ Scribed by M.A. Buldakov; I.I. Ippolitov; B.V. Korolev; I.I. Matrosov; A.E. Cheglokov; V.N. Cherepanov; Yu.S. Makushkin; O.N. Ulenikov


Book ID
103908419
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
796 KB
Volume
52
Category
Article
ISSN
1386-1425

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✦ Synopsis


A method using the symmetry properties of molecules has been developed for describing high resolution Raman spectra. This method can be applied to spontaneous Raman scattering and to nonlinear Raman scattering or resonance Raman spectroscopy. A high sensitivity laser Raman spectrometer has been constructed and some weak vibration rotation bands of diatomic molecules have been observed. The polarizability functions of N 2 and 02 are determined. The laser spectrometer has been used for gas diagnostics.


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The Raman spectrum of gaseous was recorded with charge-coupled device camera detection. The 13C 2 H 2 vibration-rotation bands of the fundamentals (in Fermi resonance with and the overtones m 1 m 2 + 2m 5 ), m 2 m 4 , 2 m 2 , and and the combinations and are presented and discussed. Some Q-branches