𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Vertical ionization potential of the CF2 radical

✍ Scribed by D.L. Hildenbrand

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
377 KB
Volume
30
Category
Article
ISSN
0009-2614

No coin nor oath required. For personal study only.

✦ Synopsis

The CF2 radical was gene&ted in an equilibrium effusion cell by tke react&m of gaseous SF6 with carbon at~l550 K. From electron impact threshold measuxm~nts, the vertiai i[P of CFZ was found to be 11.5'4 c 0.10 eV. This vaIue is

πŸ“œ SIMILAR VOLUMES

Calculations of vertical ionization pote
Calculations of vertical ionization potentials of CF4 and SiF4 by the green-function method
✍ P. Lazzeretti; R. Zanasi πŸ“‚ Article πŸ“… 1976 πŸ› Elsevier Science 🌐 English βš– 380 KB

Green-function method is empXoyed, within the framework of the CNDU approu-imation to the zero-order wavefunction, to c!dculate the photoelectron spectrum of the CF4 and SiF4 molecules, The agreement between theoretical and euperimental ionization potentials is quite good aitd a sensible ~prove~ent

Dissociation energy and ionization poten
Dissociation energy and ionization potential of the molecule CF
✍ D.L. Hildenbrand πŸ“‚ Article πŸ“… 1975 πŸ› Elsevier Science 🌐 English βš– 526 KB

Ihe gaseous equiLiirium S + CF2 = SF + CF was studied over the temperature range 18.5 L to 2232 K by mzss spectiemetry, and the derived enthalpy change was used to evaluate the heat of formation of CF AH&g8 = 58.0 + 2.4 kcal/mol (2.3& f 0.10 eV), and the dissotition energy Dt(C\_F) = 130.8 r 2.4 kca

Direct calculation of vertical ionizatio
Direct calculation of vertical ionization potentials by the coupled-cluster method
✍ Stanislav Biskupička; V. Kvasnička; R. Klein πŸ“‚ Article πŸ“… 1990 πŸ› Elsevier Science 🌐 English βš– 303 KB

The coupled-cluster method in an open-shell version with non-Hen&an model interaction is applied for direct calculation of vertical ionization potentials of closed-shell molecular systems. The theory is illustrated by calculation of vertical ionization potentials of the water molecule. The calculate