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Versatility of the Nature of the Magnetic Gadolinium(III)−Vanadium(IV) Interaction − Structure and Magnetic Properties of Two Heterobinuclear [Gd, V(O)] Complexes

✍ Scribed by Jean-Pierre Costes; Françoise Dahan; Bruno Donnadieu; Javier Garcia-Tojal; Jean-Pierre Laurent

Publisher: John Wiley and Sons
Year: 2001
Tongue: English
Weight: 229 KB
Volume: 2001
Category: Article
ISSN: 1434-1948
DOI: 10.1002/1099-0682(200102)2001:2<363::aid-ejic363>3.0.co;2-a

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✦ Synopsis

It has been known for a long time that the magnetic exchange interaction between copper and gadolinium ions is always ferromagnetic. Very recently, three exceptions to this general trend were revealed. They involve complexes associating a gadolinium(III) ion with a copper(II) ion or with rad- [a]

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