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Versatile Supramolecular Nanovalves Reconfigured for Light Activation

✍ Scribed by T. D. Nguyen; K. C.-F. Leung; M. Liong; Y. Liu; J. F. Stoddart; J. I. Zink

Book ID: 102688438
Publisher: John Wiley and Sons
Year: 2007
Tongue: English
Weight: 653 KB
Volume: 17
Category: Article
ISSN: 1616-301X
DOI: 10.1002/adfm.200600751

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Models of the iron hydrogenase active site [(-DT)Fe 2 (CO) 6 ] (DT: dithiolate) have been synthesized where the dithiolate co-factor bears a functional group to allow for their incorporation into supramolecular systems. Covalently linked to ruthenium(II) polypyridyl photosensitizers, the resulting r