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Versatile Formation of [2]Catenane and [2]Pseudorotaxane Structures; Threading and Noncovalent Stoppering by a Self-Assembled Macrocycle.

✍ Scribed by Choon Woo Lim; Shigeru Sakamoto; Kentaro Yamaguchi; Jong-In Hong


Publisher
John Wiley and Sons
Year
2004
Weight
52 KB
Volume
35
Category
Article
ISSN
0931-7597

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Self-Assembly of an Alkali Metal Cluster
✍ Snehadrinarayan Khatua; Sohaham Dasgupta; Kumar Biradha; Manish Bhattacharjee 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 209 KB

## Abstract A new tridentate ligand, {(3,5‐di‐__tert__‐butyl‐2‐hydroxybenzyl)amino}acetic acid, has been synthesized. This ligand forms [{Na~4~(H~2~O)~4~(μ‐H~2~O)~2~}(Mo~2~O~5~L~2~)~2~] (1), which contains an Na~4~^4+^ cluster cation stabilized by [LMoO~2~(μ‐O)MoO~2~L]^2–^, upon reaction with Na~2~