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Versatile Dehydrogenative Alcohol Silylation Catalyzed by Cu(I)—Phosphine Complex.

✍ Scribed by Hajime Ito; Akiko Watanabe; Masaya Sawamura


Publisher
John Wiley and Sons
Year
2005
Weight
43 KB
Volume
36
Category
Article
ISSN
0931-7597

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Stereoselective Alcohol Silylation by De
✍ Sebastian Rendler; Oliver Plefka; Betül Karatas; Gertrud Auer; Roland Fröhlich; 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 560 KB

## Abstract Ligand‐stabilized copper(I)–hydride catalyzes the dehydrogenative Si–O coupling of alcohols and silanes—a process that was found to proceed without racemization at the silicon atom if asymmetrically substituted. The present investigation starts from this pivotal observation since silico