✦ LIBER ✦
Velocity modulation laser spectroscopy of vibrationally excited CF+ determination of the molecular potential function
✍ Scribed by Martin Gruebele; Mark Polak; Richard J. Saykally
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 439 KB
- Volume
- 125
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
The lowest six vibrational hot bands of CF+ have been measured in a heIium/CsF, discharge by velocity moduiation laser spectroscopy. A total of 56 transitions has been fitted to Dunham expansion for v = O-7, yielding the parameters: we = 1792.6654(18) cm-*, Be = 1.7204176(75) cm-', r, = -13.22968(54) cm-', and D,, = 62086(30) cm-'. The rotational temperature of CFC in the plasma is near 650 K and the vibrational temperature is approximately 5200 K.