An expert system for the interpretation of infrared spectra EXPIRS was created. The main features of EXPIRS are: hierarchical organization of the characteristic groups, realized by frames; registration of the multiple use of spectral bands; taking into account the solvent absorption and the chemical
Vectorial interpretation of spectra for the study of associations
β Scribed by Ch. Marck; Ch. Schneider; L. Brehamet
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1978
- Tongue
- English
- Weight
- 486 KB
- Volume
- 17
- Category
- Article
- ISSN
- 0006-3525
No coin nor oath required. For personal study only.
β¦ Synopsis
If one considers CD spectra as vectors, then a CD spectrum may be treated as a single parameter, every wavelength entering with the same weight. The representation of a set of spectra as a vector space and the problem of the linear independence of the concentrations are discussed. Three examples of vectorial interpretation are given: determination of the number of independent molecular species; determination of the stoichiometry of a complex; and graphical representation of the overall variation of a spectrum as a function of an external parameter.
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