Single crystals of Na 3 BaCl 5 .2H 2 O were obtained from saturated aqueous solutions at two different temperatures (27Β° C and 32Β° C). The crystal size increases with increasing temperature. The crystals obtained were subjected to a systematic morphological, X-ray and thermal analyses. The study of
Various Growth Shapes of Na2S2O3 5H2O Crystals
β Scribed by T. Inoue; K. Mori; Y. Kageyama; H. Mori
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 445 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0232-1300
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β¦ Synopsis
The relation between the growth shapes and supersaturations and/or supercooloings was investigated in the Na 2 S 2 O 3 β’5H 2 O crystals: (i) The growth shapes changed from a hexagonal prismatic crystal, aggregate of platy crystals and to a spherulite with an increase of supersaturations and/or supercooloings. (ii) The deposition rate suddenly increased at a certain supersaturation and/or supercooling, where the growth shape changed from the hexagonal prism to the aggregate of platy crystals. (iii) The deposition rates of spherulites become higher with increasing the solute concentrations. (iv) The formation process of the spherulites were in situ observed by the Schlieren and/or Mach-zehnder interferometer methods.
π SIMILAR VOLUMES
Infrared spectra of and of indicate weak to moderate NΓHAE AE AEN (N 2 H 5 ) 2 HGaF 6 AE 2H 2 O ( N 2 H 5 ) 2 HFeF 6 AE 2H 2 O hydrogen bonding. Data are interpreted in terms of a double minimum symmetrical potential well with a high barrier and statistical distribution of hydrogen in the minima on