Variations and Temperature Dependence of the Excited State Properties of Conformationally and Electronically Perturbed Zinc and Free Base Porphyrins
β Scribed by Gentemann, Steve; Nelson, Nora Y.; Jaquinod, Laurent; Nurco, Daniel J.; Leung, Sam H.; Medforth, Craig J.; Smith, Kevin M.; Fajer, Jack; Holten, Dewey
- Book ID
- 126068505
- Publisher
- American Chemical Society
- Year
- 1997
- Tongue
- English
- Weight
- 300 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0022-3654
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The rational design of molecular photonic devices relies on the ability to select components with predictable electronic structure, excited state lifetimes and redox chemistry. Electronic communication in multiporphyrin arrays depends critically on the relative energies and electron density distribu
## Abstract A covalent dyad composed of a freeβbase porphyrin and a perylene diimide (**1**) was synthesised and characterised by NMR, HRMS, UV/Vis and fluorometric methods. UV/Vis spectrophotometric analysis indicated a moderate coupling between the components in the ground state. Fluorescence spe