Variation of metastable ion abundance ratios with internal energy in the mass spectrometer
β Scribed by Williams, Dudley Howard; Yeo, Adrian N. H.
- Book ID
- 126114955
- Publisher
- American Chemical Society
- Year
- 1971
- Tongue
- English
- Weight
- 715 KB
- Volume
- 93
- Category
- Article
- ISSN
- 0002-7863
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π SIMILAR VOLUMES
Calculations have been carried out, using the Quasi-Equilibrium Theory of Mass Spectra to show that a decrease in penetration of the accelerating field into the ion source of a mass spectrometer may significantly increase the number of primary daughter ions [A]+ produced from a molecular ion [MI+ in
## Abstract Certain of the βmetaβstable peaksβ in mass spectra are abnormally wide. This extra width is shown to be associated with release of kinetic energy during fragmentation. Methods are presented for measuring this energy release and values are given for various transitions in the spectra of