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Variable-Temperature Infrared Spectroscopy Studies on the Thermodynamics of CO Adsorption on the Zeolite Ca–Y

✍ Scribed by Barbara Bonelli; Carlos Otero Areán; Marco Armandi; Montserrat Rodríguez Delgado; Edoardo Garrone

Book ID
118283123
Publisher
John Wiley and Sons
Year
2008
Tongue
English
Weight
230 KB
Volume
9
Category
Article
ISSN
1439-4235

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Computational and Variable-Temperature Infrared Spectroscopic Studies on Carbon Monoxide Adsorption on Zeolite Ca-A
✍ Angeles Pulido; Petr Nachtigall; Montserrat Rodríguez Delgado; Carlos Otero Areá 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 550 KB

## Abstract **Bridged Ca**^**2+**^**⋅⋅⋅CO⋅⋅⋅Ca**^**2+**^ **complexes** are formed on dual‐cation sites, constituted by a pair of nearby Ca^2+^ cations, when CO is adsorbed on zeolite Ca‐A. Two types of such species can be formed, designated S2–S1 and S1–S1 (see picture). Ca^2+^⋅⋅⋅CO monocarbonyl sp