The standard ( p o = 0.1 MPa) molar enthalpy of combustion at T = 298.15 K of crystalline benzanthrone was determined as c H o m = -(8114.7 Β± 2.0) kJ β’ mol -1 by static-bomb calorimetry, and the standard molar enthalpy of formation of the crystal at T = 298.15 K was derived as f H o m (cr) = -(4.1 Β±
Vapour pressures, molar enthalpies of sublimation and molar enthalpies of solution in water of five halogenated derivatives of uracil
β Scribed by Piotr Szterner; Miron Kaminski; Anna Zielenkiewicz
- Publisher
- Elsevier Science
- Year
- 2002
- Tongue
- English
- Weight
- 63 KB
- Volume
- 34
- Category
- Article
- ISSN
- 0021-9614
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β¦ Synopsis
Uracil, 5-fluorouracil, 5-chlorouracil, 5-bromouracil and 6-chlorouracil (6-chloro-2,6-dihydroxypyrimidine)
, 5-iodouracil, with molar masses of 0.1121 kg β’ mol -1 , 0.1301 kg β’ mol -1 , 0.1465 kg β’ mol -1 , 0.1910 kg β’ mol -1 , 0.1465 kg β’ mol -1 , 0.2380 kg β’ mol -1 respectively, were purified by repeated crystallization. The mass fraction purity of each substance was greater than 0.99, as determined by a Du Pont 910 differential scanning calorimeter with a 1090 thermal analyzer.
π SIMILAR VOLUMES
The results of vapour-pressure measurements for several 5-alkyl derivatives of 1,3-dimethyluracil are presented along with calculated molar enthalpies of sublimation D g s Hm. The results show a nonlinear erratic dependence of D g s Hm on the number of carbon atoms in the alkyl substituent in positi
The simultaneous torsion and mass-loss effusion technique was used to measure the vapour pressure of the crystalline complexes of iron(III) with pentane-2,4-dione (HACAC) and with 2,2,6,6-tetramethylheptane-3,5-dione (HDPM), as a function of temperature, from T=369.3 K to T=387.5 K and from T=359.8
Vapour pressures as functions of temperature of seven crystalline copper(II) b-diketonates, Cuο¬2, were measured using either the Knudsen mass-loss effusion technique (Oporto apparatus), the simultaneous torsion and mass-loss effusion technique (Utrecht apparatus), or both. From the temperature depen