High pressure vapour-liquid equilibrium data for the CH 4-Ar, CH 4-CO, and Ar-CO systems are presented in this work. The data are obtained isothermally and for each data point 7", P, x i, and Yi are measured. When possible, the measurements are compared to other published data, and good agreement is
Vapour-liquid equilibria of the CH4ArCO system
✍ Scribed by L.J. Christiansen; Aa. Fredenslund
- Publisher
- Elsevier Science
- Year
- 1974
- Tongue
- English
- Weight
- 327 KB
- Volume
- 14
- Category
- Article
- ISSN
- 0011-2275
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✦ Synopsis
Isothermal-isobaric vapour-liquid equilibrium compositions were determined for the CH4-Ar-CO system at temperatures of 123.4, 137. 1, and 164.0 K and, where possible, at pressures of 10.00, 20.00, and 35.00 atm abs. At the above temperatures respectively none, one, and two of the components are supercritical. The equilibrium ratios calculated from the experimental data are found to depend strongly on temperature and pressure, whereas they depend very little on the composition. As a first approximation, the ternary phase diagram is found to be completely characterized by the constituent binary phase diagrams.
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