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(Vapour + liquid) equilibria of {1-bromo-1-chloro-2,2,2-trifluoroethane (halothane) + an oxygenated solvent or hexane}

✍ Scribed by Dana Fenclová; Vladimı́r Dohnal

Publisher: Elsevier Science
Year: 1993
Tongue: English
Weight: 242 KB
Volume: 25
Category: Article
ISSN: 0021-9614
DOI: 10.1006/jcht.1993.1067

No coin nor oath required. For personal study only.

✦ Synopsis

Isothermal (vapour + liquid) equilibria ( (p, T, x, y)) were measured for (1-bromo-1-chloro2,2,2-trifluoroethane (halothane) + propan-2-one or methyl ethanoate or methyl 1,1-dimethylethyl ether or tetrahydrofuran or hexane (}) at (T=308.15 \mathrm{~K}) by a dynamic method. Excess molar volumes were determined for {halothane + methyl 1,1-dimethylethyl ether or hexane} by calculating from density measurements at (T=298.15 \mathrm{~K}). The results obtained for the (vapour + liquid) equilibria were verified by effective statistical procedures and used to calculate activity coefficients and excess molar Gibbs free energies. The results indicate strong specific interaction of halothane with oxygenated compounds.

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