Vapor-phase dehydration of 1,5-pentanediol into 4-penten-1-ol
β Scribed by Satoshi Sato; Ryoji Takahashi; Naoki Yamamoto; Eiji Kaneko; Hirotomo Inoue
- Book ID
- 103812193
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 417 KB
- Volume
- 334
- Category
- Article
- ISSN
- 0926-860X
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3-Zircons-l-cyclopentenes and zirconacyclopentanes react with aidehydes at or below 25 OC to give the correspondmg carbonyl addition pmducts. i.e., 'I-membered oxazirconacycles, which can be readily converted to the corresponding alcohols via protonolysis and S-iodoalcohols via iodinolysis; the latt
The reactions of metastable [C,H,,OI+' radical cations produced by ionization of 4-penten-1-01 are reported and discussed. These [CSH,,O1+' species undergo mainly ethyl radical loss, with smaller contributions of methyl radical and water expulsion. \*H-Labelling studies reveal different specificitie