Significant discrepancies between van't
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Yufeng Liu; Julian M. Sturtevant
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Article
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1995
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Cold Spring Harbor Laboratory Press
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English
β 235 KB
## Abstract Isothermal calorimetric titration of 18βcrownβ6 ether with BaCl~2~ in pure aqueous solution over the temperature range 7β40 Β°C gives precise binding constants and enthalpy changes. Nonlinear leastβsquares fitting of the binding constants to the integrated van't Hoff equation, including