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van't Hoff and Calorimetric Enthalpies from Isothermal Titration Calorimetry: Are There Significant Discrepancies? †

✍ Scribed by Horn, James R.; Russell, Donald; Lewis, Edwin A.; Murphy, Kenneth P.

Book ID
120452154
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
59 KB
Volume
40
Category
Article
ISSN
0006-2960

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## Abstract Isothermal calorimetric titration of 18‐crown‐6 ether with BaCl~2~ in pure aqueous solution over the temperature range 7‐40 °C gives precise binding constants and enthalpy changes. Nonlinear least‐squares fitting of the binding constants to the integrated van't Hoff equation, including