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Vanadium oxide as a support and promoter of rhodium in synthesis gas reactions

โœ Scribed by J. Kowalski; G.v.d. Lee; V. Ponec


Book ID
119509009
Publisher
Elsevier Science
Year
1985
Weight
173 KB
Volume
19
Category
Article
ISSN
0166-9834

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Genesis of silica-supported [FesRhC(CO)t~]-and [Fe4RhC(CO)~4]-clusters with interstitial carbon atoms have been investigated in CO, syn-gas and Ar media. Complete conversion of the former cluster to the latter was obtained at 50ยฐC in any medium, with [Fe4RhC(CO)I4] cluster yielding Fe4Rh2C(CO)I 6 an