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Vanadium (IV and V) Complexes of Reduced Schiff Bases Derived from the Reaction of Aromatic o-Hydroxyaldehydes and Diamines Containing Carboxyl Groups

✍ Scribed by João Costa Pessoa; Susana Marcão; Isabel Correia; Gisela Gonçalves; Agnes Dörnyei; Tamás Kiss; Tamás Jakusch; Isabel Tomaz; M. Margarida C. A. Castro; Carlos F. G. C. Geraldes; Fernando Avecilla

Publisher: John Wiley and Sons
Year: 2006
Tongue: English
Weight: 252 KB
Volume: 2006
Category: Article
ISSN: 1434-1948
DOI: 10.1002/ejic.200600309

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## Abstract The reactions of V^V^O(O‐__i__Pr)~3~ with [PS3′]H~3~ and [PS3]H~3~ {[PS3′]H~3~ = P(C~6~H~3~‐5‐Me‐2‐SH)~3~, [PS3]H~3~ = P(C~6~H~4~‐2‐SH)~3~} led to the formation of [V^IV^(L)] [L = P2S4′ (1a), P2S4 (1b)], where L was formed by the oxidative coupling of two PS3′ or PS3 ligands by a disulf