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Vanadium-catalysed enantioselective sulfoxidations: rational design of biocatalytic and biomimetic systems

✍ Scribed by Fred van de Velde; Isabel W.C.E. Arends; Roger A. Sheldon

Book ID
110272852
Publisher
Springer
Year
2000
Tongue
English
Weight
111 KB
Volume
13
Category
Article
ISSN
1022-5528

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## Abstract Enantioselective vanadium‐catalysed oxidation of aryl benzyl sulfides using Bolm’s procedure is accompanied by kinetic resolution in the oxidation of the resulting sulfoxides which enhances the enantiopurities of the sulfoxides recovered (typically >90 % __ee__), albeit with an associat