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Vanadium bromoperoxidases mimicking systems: Bromohydrins formation as evidence of the occurrence of a hypobromite-like vanadium complex

✍ Scribed by Malin Andersson; Valeria Conte; Fulvio Di Furia; Stefano Moro


Publisher
Elsevier Science
Year
1995
Tongue
French
Weight
226 KB
Volume
36
Category
Article
ISSN
0040-4039

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Vanadium-Bromoperoxidase-Mimicking Syste
✍ Olga Bortolini; Mauro Carraro; Valeria Conte; Stefano Moro πŸ“‚ Article πŸ“… 2003 πŸ› John Wiley and Sons 🌐 English βš– 127 KB

## Abstract Here we report a direct observation, by electrospray ionization mass spectrometry, of the intermediate [VO(OH~2~)(OH)(OBr)]^+^, which may be involved in the catalytic cycle of the V‐HalPO enzymes. Ab initio calculations also support the stability of such a species. (Β© Wiley‐VCH Verlag G