Vanadium-Bromoperoxidase-Mimicking Syste
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Olga Bortolini; Mauro Carraro; Valeria Conte; Stefano Moro
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Article
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2003
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John Wiley and Sons
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English
β 127 KB
## Abstract Here we report a direct observation, by electrospray ionization mass spectrometry, of the intermediate [VO(OH~2~)(OH)(OBr)]^+^, which may be involved in the catalytic cycle of the VβHalPO enzymes. Ab initio calculations also support the stability of such a species. (Β© WileyβVCH Verlag G