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Values and signs of 13C, 1H spin-spin coupling constants in 1,6,6aλ4-trithiapentalene and 1,6-dioxa-6aλ 4-thiapentalene

✍ Scribed by T. Bjorholm; J. P. Jacobsen

Publisher
John Wiley and Sons
Year
1981
Tongue
English
Weight
197 KB
Volume
17
Category
Article
ISSN
0749-1581

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✦ Synopsis

Abstract

The values and signs of ^13^C, ^1^H spin‐spin coupling constants in 1,6,6aλ^4^‐trithiapentalene and 1,6‐dioxa‐6aλ^4^‐thiapentalene have been re‐investigated. The contributions from second order effects in the spectra have been included in an iterative spectral analysis. The values found deviate significantly from the values found earlier by first order analysis. The signs of the spin‐spin coupling constants have been established by the use of the SPT technique.

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