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Validity of the rotating wave approximation for high-order molecular multiphoton processes

✍ Scribed by Israel Schek; Martin L. Sage; Joshua Jortner


Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
604 KB
Volume
63
Category
Article
ISSN
0009-2614

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✦ Synopsis


We e_xambze t& suIIicient conditkms for the appliclbdity of the rotaticg wave approximation (RWA) for high-order multiphoton exfitation (HOME) cif a -many4evel mdecular level structure. and demonstrate the breakdown of the R\YA for HOIS of the entire bound spectrum of a hforse osfilijtor_ \ve propose that the Magnus eApan.sion for the timeevoiution operator provides a useful, practical and powerful method to surpass the R\IA.