Validity of Lee, Low and Pines Method in the Case of the Interaction of an Electron with a Single Lattice Oscillator
β Scribed by J. Devreese; R. Evrard
- Book ID
- 105385688
- Publisher
- John Wiley and Sons
- Year
- 1963
- Tongue
- English
- Weight
- 530 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0370-1972
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β¦ Synopsis
Abstract
The LEEβLOWβPINES approximation (or LLP approximation) of polaron theory is applied to a model first studied by GROSS, in which the polarization field is supposed to have only one kβcomponent. The results are compared with the exact solutions obtained with GROSS' method. It is shown that, in the particular case of this model, the LLP approximation is not very satisfactory when the mean number of phonons is of the order of, or greater than, 1/2. Thus the relative smallness of the mean number of virtual phonons cannot provide an argument for the validity of the LLP method in the intermediate coupling region.
π SIMILAR VOLUMES
## Abstract A perturbation configuration interaction method is formulated for a system in an external oscillating field (PCILOSC). It is closely connected with the static PCILO method and can be used for the conformational analysis of molecules and molecular crystals with localized bonds in externa