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Validation of Lanthanoid Chiral Shift Reagents for Determination of Absolute Configuration: Total Synthesis of Glisoprenin A.

โœ Scribed by Christopher M. Adams; Indranath Ghosh; Yoshito Kishi

Book ID
101972040
Publisher
John Wiley and Sons
Year
2005
Weight
8 KB
Volume
36
Category
Article
ISSN
0931-7597

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Absolute configuration of aldonic acids
Absolute configuration of aldonic acids and lanthanoid induced shift by the chiral shift reagent propylenediaminetetraacetatoeuropium(III) in aqueous solution
โœ Kuninobu Kabuto; Kazuo Sasaki; Yoichi Sasaki ๐Ÿ“‚ Article ๐Ÿ“… 1992 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 284 KB

Consistent relation was observed between the absolute configuration of seventeen aldonic acids and their lH NMR shifts induced by chiral propylenediaminetetraacetatoeuropium(Ii1) in aqueous solution. Recent advance in NMR methods for determining absolute configuration has made it possible to apply