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Valence Tautomerism in a o-Benzoquinone Adduct of a Tetraazamacrocycle Complex of Manganese

✍ Scribed by Andrea Caneschi; Andrea Dei


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
110 KB
Volume
37
Category
Article
ISSN
0044-8249

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An electronic switch at the molecular level has been realized by using a class of ionic compounds of the formula [Co(L)(diox)]Y (L tetraazamacrocyclic ligand, Y mononegative anion). Such compounds undergo temperature-and pressure-induced intramolecular one-electron transfer equilibria. The transitio