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Valence tautomeric cobalt o-quinone complexes in a dual-mode switching array

✍ Scribed by Ruiz, Daniel; Yoo, Jae; Hendrickson, David N.; Guzei, Ilia A.; Rheingold, Arnold L.


Book ID
121507739
Publisher
Royal Society of Chemistry
Year
1998
Tongue
English
Weight
77 KB
Volume
19
Category
Article
ISSN
1359-7345

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An electronic switch at the molecular level has been realized by using a class of ionic compounds of the formula [Co(L)(diox)]Y (L tetraazamacrocyclic ligand, Y mononegative anion). Such compounds undergo temperature-and pressure-induced intramolecular one-electron transfer equilibria. The transitio