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Valence shell orbital imaging in adamantane by electron momentum spectroscopy

✍ Scribed by Igor V. Litvinyuk; Y. Zheng; C.E. Brion


Book ID
108430891
Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
390 KB
Volume
253
Category
Article
ISSN
0301-0104

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The electron density in each of the outermost MOs of N( CH3)3 and NFS, as measured by electron momentum spectroscopy, is found to exhibit a very much higher degree of s character than the corresponding orbital in NHj. This behaviour is clearly predicted by MO calculations which indicate appreciable