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Valence orbital ionization potentials from atomic spectral data

✍ Scribed by Harold Basch; Arlen Viste; Harry B. Gray


Publisher
Springer
Year
1965
Tongue
English
Weight
434 KB
Volume
3
Category
Article
ISSN
1432-2234

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Ab initio model potential calculations on X-, X, and X+ (X = F, Cl, Br, and I) using CISD wavefunctions have been performed in order to test a recent conclusion on the irrelevance of the valence orbital internal nodes in the values of atomic valence correlation energies. The results show that the ab