Vacuum UV photoisomerization of cis-2-butene in the presence of sulfur hexafluoride
โ Scribed by H. Gagnon; G.J. Collin
- Publisher
- Elsevier Science
- Year
- 1976
- Weight
- 104 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0047-2670
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Cisand trans-buten-2-yl free radicals are shown to react with D2S in metathetical steps: Relative formation rates of monodeuteriated butenes in D2S -2 -C,Hs mixtures were measured at low extent of reaction in the experimental range: 20-200 torr 2 -C4Hs, 0-41-torr D2S and 717-817 K. In these pressur
Cis-and trans-buten-2-yl free radicals are shown to react with butene-2 cis (B,) and D2S in the following metathetical steps: ## D giving rise to butenes-1 (B1). The initial formations of butene-1,3 d, and total butene-1 in D2S-B, mixtures have been studied in the initial pressure range 20-200 to