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Vacancy pairs and correlation effects in KCl and NaCl single crystals

✍ Scribed by Michelle Beniere; Marius Chemla

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
210 KB
Volume
17
Category
Article
ISSN
0038-1098

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EPR of palladium(I) and palladium(III) cyanide complexes in NaCl and KCl single crystals
✍ N.V. Vugman; M.L.Netto Grillo; V.K. Jain 📂 Article 📅 1988 🏛 Elsevier Science 🌐 English ⚖ 404 KB

The EPR spectra of X-ray-irradiated single crystals of NaCl and KC1 doped with cyanide complexes of Pd have been studied at 77 K. The measured g and A values indicate the formation of [ Pd( CN),C12] "-(n= 3, 5 ) complexes. Ligand field parameters and spin densities have been estimated for the oxidiz