UV photoelectronspectra of square planar complexes of the Nickel triad metals
✍ Scribed by A. Oskam; D.J. Stufkens; J.N. Louwen
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- English
- Weight
- 96 KB
- Volume
- 142
- Category
- Article
- ISSN
- 0022-2860
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## Abstract The NHC‐stabilized C–F activation product [Ni(__i__Pr~2~Im)~2~(F)(C~6~F~5~)] (1) was isolated from the reaction of [Ni(cod)~2~] with 1,3‐diisopropylimidazol‐2‐ylidene (__i__Pr~2~Im) and hexafluorobenzene. Square‐planar (pentafluorophenyl)nickel complexes of the type [Ni(__i__Pr~2~Im)~2~
## Abstract Na[__cyclo__‐(P~5~__t__Bu~4~)] (1) reacts with [NiCl~2~(PEt~3~)~2~] and [PdCl~2~(PMe~2~Ph)~2~] with elimination of __t__BuCl and formation of the corresponding metal(0) cyclopentaphosphene complexes [Ni{__cyclo__‐(P~5~__t__Bu~3~)}(PEt~3~)~2~] (2) and [Pd{__cyclo__‐(P~5~__t__Bu~3~)}(PMe~