UV photoelectron spectra of some substituted iron dithiocarbamates

✍ Scribed by C. Cauletti; N.V. Duffy; C.L. Furlani

• Publisher: Elsevier Science
• Year: 1977
• Tongue: English
• Weight: 314 KB
• Volume: 23
• Category: Article
• ISSN: 0020-1693
• DOI: 10.1016/s0020-1693(00)94758-3

✦ Synopsis

Photoelectron spectra (He(I)) are reported for several Fe(dtc)z(CO)z complexes, which, in vapor phase under experimental p. e. spectroscopic conditions, lose their CO and behave as Fe(dtc)z (dtc-= N,N'disubstituted dithiocarbamate anion). p.e. Spectra are not well resolved, but can be interpreted on the ground of a comparison with already known transition-metal diethyldithiocarbamates.

Substituent effects due to the groups bonded to the dithiocarbarnate nitrogen are particularly large, and their possible mechanisms are discussed.