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UV-Induced Desorption-Retrapping Cycle of Electrochemically Adsorbed CO on Pt(111) Surface

✍ Scribed by Ohta, N.; Yu, Q.-K.; Nakabayashi, S.

Book ID
126267376
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
109 KB
Volume
105
Category
Article
ISSN
0022-3654

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Surface diffusion of deuterium and hydrogen on Pt(ll1) has been investigated by laser-induced thermal desorption. As the initial surface coverage of deuterium is varied from 0.001 to 0.33, the diffusional activation energy falls from 12 to 7 kcal/mol, and the pre-exponential factor falls from 3 x lo