Utilization of the chemical properties of liquid matrices to investigate reductive processes in fast atom bombardment mass spectra

Reduction by Electron and Hydride Attach

Reduction by Electron and Hydride Attachment to Doubly Charged Heterocyclic Cations in Fast-atom Bombardment Mass Spectrometry. Influence of the Matrix

✍ Pilar Cabildo; Rosa Claramunt; Dionisia Sanz; José Elguero; Christine Enjalbal; 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 308 KB 👁 2 views

A study of the fast-atom bombardment spectra of positive ions which result from doubly charged heterocyclic cationic compounds shows the influence of the matrix on the nature of the spectrum. While two reduction reactions are encountered with glycerol (electron and hydride anion attachment), the spe